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Thermodynamic calculation and viscosity measurements show that with the increase of Fe 2O 3 content, m(CaO)/ m(SiO 2), and m(SiO 2)/ m(Al 2O 3), the depolymerization of silicate network structure and low-melting-point phase transformation first occur within the slag, leading to the decrease in melting point and viscosity of the slag, while further increase causes the formation of high-melting-point phase and a resultant re-increase in viscosity and melting point.

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Experimental results show that the increase of Fe 2O 3 content (3.8wt%–16.6wt%), the mass ratio of CaO/SiO 2 ( m(CaO)/ m(SiO 2), 0.5–1.3), and the mass ratio of SiO 2/Al 2O 3 ( m(SiO 2)/ m(Al 2O 3), 1.0–5.0) can promote the depolymerization of silicate network, and the presence of a large amount of Fe 2O 3 in form of tetrahedral and octahedral units ensures the charge compensation of Al 3+ ions and makes Al 2O 3 only behave as an acid oxide. The slag structure, melting temperature, and viscous characteristics were investigated by Fourier transform infrared (FTIR) spectroscopy, Raman spectroscopy, FactSage calculation, and viscosity measurements. The metallurgical properties of the CaO–SiO 2–Al 2O 3–4.6wt%MgO–Fe 2O 3 slag system, formed by the co-treatment process of spent automotive catalyst (SAC) and copper-bearing electroplating sludge (CBES), were studied systematically in this paper.









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